SDS ARGEDENT 52

Safety Data Sheet
(REACH Regulation (EC) N° 1907/2006 - N° 453/2010)

Effective Date: March 30, 2017

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1	Product identifier
	Product name: ARGEDENT 52
1.2.	Relevant identified uses of the substance or mixture and uses advised against
	Relevant identified uses of the substance or mixture Manufacturing of a fixed or removable dental prosthesis in a dental laboratory
1.3.	Details of the supplier of the safety data sheet
	Manufacturer: Company name: The Argen Corporation Full address: 5855 Oberlin Drive, San Diego, CA 92121-4718. USA Technical Service: 1-800-255-5095 Customer Care: 1-800-255-5095 Fax: 1-858-626-8686 E-mail address of competent person responsible for the SDS: info@argen.com
1.4.	Emergency telephone number
	Emergency telephone number: Chemtrec: 1-703-741-5970 (collect calls accepted)

SECTION 2: Hazards identification

2.1.

Classification of the substance or mixture

Classification information
This product does not meet the classification criteria in (EC) N° 1272/2008 (CLP)
This product does not meet the labeling criteria stated in 67/548/EWG and 1999/45/EC

2.2.

Label elements

Labeling is in accordance with (EC) No 1272/2008 (CLP Regulation). Label elements in the solid form which the product is marketed

2.3.

Other hazards


EYES	Contact with eyes may cause severe irritation and possible eye burns.
SKIN:	May cause severe irritation and possible burns.
INGESTION:	May cause gastrointestinal irritation with nausea, vomiting, and diarrhea.
INHALATION:	May cause irritation and burns to the respiratory tract.

SILVER

Absorption of silver compounds by ingestion, inhalation or through broken skin can cause argyria, a permanent bluish-grey discoloration of the skin, conjuctiva and mucous membranes. Generalized argyria develops after 2 to 25 years of exposure. There are no systematic effects or symptoms and no physical disability. Silver is considered an experimental equivocal tumorigenic agent by RTECS criteria.

INDIUM

May cause fetal effects based upon animal studies. May cause lung damage and blood abnormalities. Target Organs: Blood, kidneys, liver, lungs.

RUTHENIUM

The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.

PBT assesment
No data available

vPvB assessment
No data available

SECTION 3: Composition/information on ingredients

3.1.

Substances

This product is not a substance ‑ This is not applicable

3.2.

Mixtures

Ingredients:

METAL	%	SYMBOL	CAS NO	EC/EG NO	ACGIH 8 HR TLV	OSHA 8 HR PEL

GOLD	52.5	Au	7440-57-5	231-165-9	Not established	Not established
PALLADIUM	26.9	Pd	7440-05-3	231-115-6	No data	No data
SILVER	16	Ag	7440-22-4	231-131-3	0.01 mg/m3	0.1 mg/m3
RUTHENIUM	<1	Ru	7440-18-8	231-127-1	No data	No data
INDIUM	2.5	In	7440-74-6	231-180-0	0.1 mg/m3	0.1 mg/m3 TWA
TIN	2	Sn	7440-31-5	231-141-8	2 mg/m3	2 mg/m3

Note: % values are in weight percent and reflect nominal composition.

Note: 'x' denotes a content of less than one percent

SECTION 4: First aid measures

4.1.

Description of first aid measures

EYE CONTACT:	Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids.
SKIN CONTACT:	Scrub skin thoroughly with soap and water. If victim is conscious and alert, give 2-4 cupfuls of milk or water
INGESTION:	If victim is conscious and alert, give 2-4 cupfuls of milk or water. Induce vomiting. **Never give anything by mouth to an unconscious person. Get medical aid.
INHALATION:	Remove affected person to fresh air and assist with additional oxygen if necessary. Get first aid if other symptoms appear.

4.2.

Most important symptoms and effects, both acute and delayed

No data available

4.3.

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Fire-fighting measures

5.1.	Extinguishing media
	Metal fire powders, sand
5.2.	Special hazards arising from the substance or mixture
	Heating Beyond the melting range may generate fumes which are not flammable
5.3.	Advice for fire-fighters
	Wear protective clothing and use a self-contained breathing apparatus

SECTION 6: Accidental release measures

6.1.	Personal precautions, protective equipment and emergency procedures
	For non-emergency personnel Use proper personal protective equipment as described in section 8. For emergency responders Use proper personal protective equipment as described in section 8.
6.2.	Environmental precautions
	Collect contaminated materials in separate containers. Discharge according to local regulations.
6.3.	Methods and material for containment and cleaning up
	Avoid creating dust and pick-up using mechanical means
6.4.	Reference to other sections
	No data available

SECTION 7: Handling and storage

7.1.	Precautions for safe handling
	Ensure the workspace has proper ventilation Do not consume substances during work. General protective and hygiene measures Wash hands before and after breaks. Remove contaminated clothing immediately. Do not ingest, or allow to come into contact with the eyes.
7.2.	Conditions for safe storage, including any incompatibilities
	Keep container closed in a ventilated area
7.3.	Specific end use(s)
	No data available

SECTION 8: Exposure controls/personal protection

8.1.

Control parameters

Occupational exposure limit values

8.2.

Exposure controls

RESPIRATORY:	RESPIRATORY: Provide general ventilation and local exhaust to keep levels below the TLV stated in SECTION 3. Wear a NIOSH approved respirator for dust exceeding the TLVs.
	Latex gloves are recommended while grinding, heat resistant gloves should be worn while casting and handling hot metals or molds.
EYE PROTECTION:	Wear eye protection suitable to each individual operation.
OTHER:	Wear apron, lab coat or other protective clothing.

SECTION 9: Physical and chemical properties

9.1.

Information on basic physical and chemical properties

Appearance:	WHITE
Odor:	Not Applicable
pH:	Not Applicable
Boiling Point:	Not Applicable
Melting Range:	1205-1260 °C
Flash Point:	Not Applicable
Flammability:	Not Applicable
Autoflammability:	Not Applicable
Explosive Properties:	Not Applicable
Oxidizing Properties:	Not Applicable
Vapor Pressure:	Not Applicable
Solubility(Water/Fat):	Insoluble

9.2.

Other information

No data available

SECTION 10: Stability and reactivity

10.1.	Reactivity
	At ordinary and high (below the melting range) temperatures, the material oxidizes but is stable. At very high temperatures the alloy produces fumes.
10.2.	Chemical stability
	Product is stable under normal storage and handling conditions. See Section 7.
10.3.	Possibility of hazardous reactions
	Hydrogen gas can possibly form if the product comes into contact with acid
10.4.	Conditions to avoid
	N/A if the product is handled according to the Instructions for Use
10.5.	Incompatible materials
	Acid
10.6.	Hazardous decomposition products
	None are known

SECTION 11: Toxicological information

11.1.	Information on toxicological effects
	No data is available other than the information provided in Sections 2 and 3

SECTION 12: Ecological information

12.1.	Toxicity
	No data available
12.2.	Persistence and degradability
	No data available
12.3.	Bio-accumulative potential
	No data available
12.4.	Mobility in soil
	No data available
12.5.	Results of PBT and vPvB assessment
	No data available
12.6.	Other adverse effects
	No data available

SECTION 13: Disposal considerations

13.1.	Waste treatment methods
	Product: Always recover all waste material and send to Department A at The Argen Corporation for refining. Packaging: Empty container completely and dispose according to local regulations.

SECTION 14: Transport information

14.1.	Transport ADR/RID/AND
	This product is not subject to ADR/RID/AND regulations
14.2.	Transport IMDG
	This product is not subject to IMDG regulations
14.3.	Transport ICAO-TI / IATA
	This product is not subject to ICAO-Ti / IATA regulations
14.4.	Other information
	No data available
	No data available
14.5.	Environmental hazards
	No data is available other than the information provided in Sections 2 and 3
	This product is not subject to ICAO-Ti / IATA regulations
14.6.	Special precautions for user
	none
14.7.	Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
	Not applicable

SECTION 15: Regulatory information

15.1.	Safety, health and environmental regulations/legislation specific for the substance or mixture
	Germany: Wassergefährdungsklasse WGK (VwVwS): WGK-1 (self-assessed)
15.2.	Chemical Safety Assessment
	No Chemical Safety Assessment has been carried out for this substance/mixture by the supplier.

SECTION 16: Other information

16.1.	Training advice
	In addition to health, safety and environmental training programs for their workers, companies must ensure that workers read, understand and apply the requirements of this SDS.
16.2.	Disclaimer
	The information and recommendations set forth herein (hereinafter "information") are presented in good faith and believed to be correct as of the date hereof. However, THE ARGEN CORPORATION makes no representations as to the completeness of accuracy thereof and information is supplied upon the condition that the persons receiving the above material will make there own determination as to its suitability for their purposes prior to use. In no event will "THE ARGEN CORPORATION" be responsible for damages of any nature whatsoever resulting from the use of or reliance upon information. No representations or warranties, either expressed or implied, or merchantability, fitness for a particular purpose or of any other nature are made hereunder with respect to information or the product to which information refers.